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991.
Sergei V. Shirin Oleg L. Polyansky Nikolai F. Zobov Roman I. Ovsyannikov Jonathan Tennyson 《Journal of Molecular Spectroscopy》2006,236(2):216-223
Adiabatic potential energy surfaces (PESs) for three major isotopologues of water, H216O, H217O, and H218O, are constructed by fitting to observed vibration-rotation energy levels of the system using the nuclear motion program DVR3D employing an exact kinetic energy operator. Extensive tests show that the mass-dependent ab initio surfaces due to Polyansky et al. [O.L. Polyansky, A.G. Császár, S.V. Shirin, N.F. Zobov, P. Barletta, J. Tennyson, D.W. Schwenke, P.J. Knowles, Science 299 (2003) 539-542.] provide an excellent starting point for the fits. The refinements are performed using a mass-independent morphing function, which smoothly distorts the original adiabatic ab initio PESs. The best overall fit is based on 1788 experimental energy levels with the rotational quantum number J = 0, 2, and 5. It reproduces these levels with a standard deviation of 0.079 cm−1 and gives, when explicit allowance is made for nonadiabatic rotational effects, excellent predictions for levels up to J = 40. Theoretical linelists for all three isotopologues of water involved in the PES construction were calculated up to 26 000 cm−1 with energy levels up to J = 10. These linelists should make an excellent starting point for spectroscopic modelling and analysis. 相似文献
992.
1,1‐Dibromo‐2,2‐bis(trimethylsilylethynyl)ethene ( 2 ) reacts with two equivalents of 1‐boraadamantane ( 1 ) by 1,1‐organoboration of both trimethylsilylethynyl groups to give a triene 3 bearing two 4‐methylene‐3‐borahomoadamantane moieties in terminal positions. The triene was characterized by one‐ and two‐dimensional 1H, 11B, 13C and 29Si NMR spectroscopy in solution and X‐ray structural analysis in the solid state. The planes of the C double bond are strongly twisted against each other as a result of the bulky substituents, and the surroundings of the boron atoms deviate from the ideal trigonal planar geometry owing to the tension in the tricyclic frameworks. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
993.
Cu(2)O nanowires in an alumina template: electrochemical conditions for the synthesis and photoluminescence characteristics. 总被引:1,自引:0,他引:1
Cu2O nanowires, mainly consisting of (100) and (200) polycrystalline structures with a length of 4 mum are prepared by electrochemical deposition using a porous alumina template. It is found that the optimized electrochemical conditions to prepare Cu2O nanowires are different from those for the formation of a bulk thin Cu2O layer since different pH values are found between the tip of the pores and the bulk, due to diffusion limits in porous alumina with an extremely high aspect ratio of 300. We point out that Cu2O (200), Cu2O (111), Cu, and co-deposited alloys can be obtained under specific electrochemical conditions. In addition, the optical band gap of the prepared Cu2O nanowires with a length of 4 microm and a diameter of 200 nm is estimated to be 2.17 eV from photoluminescence measurements. 相似文献
994.
《Magnetic resonance in chemistry : MRC》2002,40(3):231-236
The assignments of 1H and 13C NMR chemical shifts together with x‐ray diffraction data for synthesized diosgenyl 3,4,6‐tri‐O‐acetyl‐2‐deoxy‐2‐tetrachlorophthalimido‐β‐D ‐glucopyranoside are described. The structure of this glycoside was established by using homo‐ and heteronuclear two‐dimensional NMR techniques. X‐ray diffraction data for this compound are also reported. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
995.
P. Bonifazi 《Il Nuovo Cimento C》1990,13(1):35-47
Summary The data obtained with three highly sensitive gravitational wave antennas have been used to establish an improved observational
upper limit on the flux of impulsive gravitational waves. Preliminary results under the assumption of a source located in
the center of the Galaxy are also reported.
To speed up publication, the proofs were not sent to the authors and were superised by the Scientific Committee. 相似文献
996.
In this work we establish the limiting absorption principle for the two-dimensional steady-state elasticity system in an inhomogeneous aniso- tropic medium. We then use the limiting absorption principle to prove the existence of a radiation solution to the exterior Dirichlet or Neumann boundary value problems for such a system. In order to define the radiation solution, we need to impose certain appropriate radiation conditions at infinity. It should be remarked that even though in this paper we assume that the medium is homogeneous outside of a large domain, it still preserves anisotropy. Thus the classical Kupradze's radiation conditions for the isotropic system are not suitable in our problem and new radiation conditions are required. The uniqueness of the radiation solution plays a key role in establishing the limiting absorption principle. To prove the uniqueness of the radiation solution, we make use of the unique continuation property, which was recently obtained by the authors. The study of this work is motivated by related inverse problems in the anisotropic elasticity system. The existence and uniqueness of the radiation solution are fundamental questions in the investigation of inverse problems.
997.
In this paper we study the homogeneous relativistic heat equation (HRHE) obtained as asymptotic limit of the so-called relativistic
heat equation (RHE) when the kinematic viscosity ν → ∞. These equations were introduced in the theory of radiation hydrodynamics
to guarantee a bounded speed of propagation of radiating energy. We shall prove that this is indeed true, and we shall construct
some explicit solutions of the HRHE exhibiting fronts propagating at light speed. 相似文献
998.
For the first time, the dissipation of laser-radiation energy in the gas surrounding a target is investigated under the conditions
of intense plasma formation near a surface and the existence of large spots of: irradiation. The parameters of different regions
of the heated gas are measured and an energy balance of the process of laser effects is obtained.
Institute of Molecular and Atomic Physics, National Academy of Sciences of Belarus, 70, F. Skorina Ave., Minsk, 220072, Belarus.
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 65, No. 6, pp. 814–817, November–December, 1998. 相似文献
999.
1000.